Sam Levine on Nostr: "After that, we examined three different solvents (Table 1, entries 8 and 9), ...
"After that, we examined three different solvents (Table 1, entries 8 and 9), interestingly, none of the other aprotic polar solvents afforded the product except DMSO."
The second step in the cascade/mechanism is a freakin' Kornblum oxidation!!! Of course you didn't get product without DMSO!!!
*sigh*
Guess I'll have to test other solvents myself with DMSO as an additive because this was a useless piece of data.
#Chemistry #ChemiVerse
Published at
2024-07-31 17:57:25Event JSON
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